The Journal of Physical Chemistry C 2022, Article ASAP. Understanding the Photoelectrochemical Behavior of Metal Nanoclusters: A Perspective.
This article is cited by 17 publications. The work provides a paradigm that the NCs with continuous metal atom numbers are accessible and crystallizable when meticulously designed, and the optical properties are more affected at the single atom level than the electronic properties.
A.t.o.m. show series#
By contrast, little change in both ionization potential and electron affinity is found in this series of NCs by theoretical calculations, indicating the electronic properties are independent of adding a single atom in this series. The photoexcited carrier lifetime demonstrates that the optical properties and excited state relaxation are highly sensitive at the single atom level. A single Cd atom triggers the structural transition from Au 22 with a 10-atom bioctahedral kernel to Au 22Cd 1 with a 13-atom cuboctahedral kernel, and correspondingly, the optical properties are dramatically changed. Structurally, Au 22(SAdm) 16 has an Au 3(SAdm) 4 surface motif which is longer than the Au 2(SAdm) 3 on Au 21(SAdm) 15, whereas Au 22Cd 1(SAdm) 16 lacks one staple Au atom compared to Au 24(SAdm) 16 and thus the surface structure is reconstructed. Here, we report crystallizations of Au 22(SAdm) 16 and Au 22Cd 1(SAdm) 16 (SAdm = adamantanethiolate) which link up with Au 21(SAdm) 15 and Au 24(SAdm) 16 NCs and form an atom-by-atom evolving series protected by the same ligand. G Mitchell – Celestial Highways (Metroplex)ġ1.Atom-by-atom manipulation on metal nanoclusters (NCs) has long been desired, as the resulting series of NCs can provide insightful understanding of how a single atom affects the structure and properties as well as the evolution with size. Omar S – Give It To Me (FXHE MUSIC ASCAP 003)ġ0. Remote Viewing Party – Up Thing (DEQ Detroit Electronic Quarterly)Ġ8. Jeffrey Scott – Under Aqua (Sheik ‘N’ Beik) A1Ġ7. Smoke & Mirrors – John DImas Remix (Overall Music)Ġ5. MJOG – Recordeep Hors Serie 01 (Recordeep) A1Ġ4. Stewart S Walker – Boring Movies (Tresor 146)Ġ3. Peace for Earth – Four Tet (Text Records) A1Ġ2. He is currently working on music releases for his labels “Castaway Recordings” and “Oily Records”.Ġ1. He managed to rock his live act at festivals like “Okeechobee Music Festival”, the iconic “III Points” in Miami and the newly born “Rapture Music Festival” where he and his team have the “Castaway Stage”. He is frequently invited to play in the hot spots for electronic music in the city. He holds residencies at “Floyd Miami”, “The Ground” at “Club Space” & “Castaway” island party. Atom is one of the most active DJs in the Miami underground scene. He can be seen rocking the guitar, singing his original music or rocking dance floors with his energetic Dj act. His motto “think outside the club” is the drive for his parties.Ītom is well known for his versatility. He and his team have managed to take hundreds of dancers to exclusive yacht parties and isolated islands where the music is what matters.
Half brain of Speaker Box Productions and co-creator of “Castaway” and “On-Deck” boat parties. Atomyard lives and works in Miami as a club Dj, musician and recording artist.
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